PFAC-MXB, a native PFAS mixture standard solution, was purchased from Wellington Laboratories Inc. (Guelph, ON, Canada). Perfluorobutane sulfonic acid (PFBS), perfluorohexanesulfonic acid (PFHxS), perfluorooctanesulfonic acid (PFOS), perfluorodecanesulfonic acid (PFDS), perfluorobutanoic acid (PFBA), perfluoropentanoic acid (PFPeA), perfluorohexanoic acid (PFHxA), perfluoroheptanoic acid (PFHpA), perfluorooctanoic acid (PFOA), perfluorononanoic acid (PFNA), perfluorodecanoic acid (PFDA), perfluoroundecanoic acid (PFUnDA), perfluorodecanoic acid (PFDoDA), perfluorotridecanoic acid (PFTrDA), perfluorotetradecanoic acid (PFTeDA), perfluorohexadecanoic acid (PFHxDA), perfluorooctadecanoic acid (PFOcDA), individual native standards, perfluorooctane sulfonamide (FOSA), N-ethyl perfluorooctane sulfonamide (
N-EtFOSA), and N-ethyl perfluorooctane sulfonamide acetic acid (
N-EtFOSAA) were procured from the same source.
The mass-labeled standard mixtures MPFAC-MXA, consisting of
18O
2-PFHxS,
13C
4-PFOS,
13C
4-PFBA,
13C
2-PFHxA,
13C
4-PFOA,
13C
5-PFNA,
13C
2-PFDA,
13C
2-PFUnDA, and
13C
2-PFDoDA, and individual mass-labeled standards,
13C
3-PFBS and
13C
5-PFPeA, were purchased from Wellington Laboratories Inc. (Guelph, ON, Canada). All compounds had >98% purity.
Oasis
® weak anion exchange (WAX; 6 cc, 150 mg, 30 μm) solid-phase extraction (SPE) cartridges (Waters Corp., Milford, MA, USA),
Supelclean ENVI-Carb (100 mg, 1 mL) cartridges (Sigma-Aldrich Corp., St. Louis, MO, USA), ammonium acetate (97%; Wako Pure Chemical Industries Ltd., Osaka, Japan), ammonium solution (25%; Wako Pure Chemical Industries Ltd., Osaka, Japan), acetic acid (>99.7%; guaranteed reagent; Wako Pure Chemical Industries Ltd., Osaka, Japan), ultrapure water (prepared with a Milli-Q
® gradient system; Millipore Co., Bedford, MA, USA), and methanol (>99.8%; pesticide residue-PCB analytical grade; Wako Pure Chemical Industries Ltd., Osaka, Japan) were used in all experiments and instrumental analyses.
Eun H., Yamazaki E., Pan Y., Taniyasu S., Noborio K, & Yamashita N. (2022). Evaluating the Distribution of Perfluoroalkyl Substances in Rice Paddy Lysimeter with an Andosol. International Journal of Environmental Research and Public Health, 19(16), 10379.