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2 protocols using «β cyclodextrin»

1

Synthesis of β-CD-PAMAM Conjugates

2020
All starting materials were commercially available reagent grade and were used without any further purification. β-Cyclodextrin (β-CD), PAMAM dendrimer G1 (PAMAM G1), propargyl bromide solution (80% by weight in toluene), p-toluenesulfonyl chloride (Cl-Ts), p-toluenesulfonic acid (OH-Ts), methyl 2-(4-hydroxyphenyl)acetate, N,N-dimethylformamide anhydrous (DMF), anhydrous potassium carbonate (K2CO3), dimethylsulfoxide (DMSO), ascorbic acid (H2Asc), N-(3-dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride (EDC·HCl), Bio-Gel P-10 medium from BIO-RAD, 1-hydroxybenzotriazole hydrochloride (HOBt·HCl), N,N-diisopropylethylamina (DIPEA), potassium iodide (KI), sodium azide (NaN3), sodium hydroxide (NaOH), copper sulfate pentahydrate (CuSO4·5H2O), dichloromethane (CH2Cl2), methanol (MeOH), ethanol (EtOH) and acetone (CH3COCH3) were purchased from Sigma-Aldrich.
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2

Synthesis and Functionalization of Cyclotriphosphazenes

2020
All starting materials were commercially available reagent grade and were used without any further purification. Hexachlorocyclotriphosphazene (P3N3Cl6), 5-chloro-1-pentyne, 6-iodo-1-hexyne, hydroquinone, β-cyclodextrin (βCD), p-toluenesulfonyl chloride (Cl-Ts), p-toluenesulfonic acid (OH-Ts), N,N-dimethylformamide anhydrous (DMF), potassium carbonate (K2CO3), cesium carbonate (Cs2CO3), dimethylsulfoxide (DMSO), ascorbic acid (H2Asc), Bio-Gel P-10 medium from Bio-Rad (Hercules, CA, USA), potassium iodide (KI), sodium azide (NaN3), sodium hydroxide (NaOH), copper sulfate pentahydrate (CuSO4•5H2O), diisopropyl ether, dichloromethane (CH2Cl2), ethyl acetate (EtOAc), tetrahydrofuran anhydrous (THF), hexane (HEX), methanol (MeOH), ethanol (EtOH) and acetone (CH3COCH3) were purchased from Sigma-Aldrich (St. Louis, MO, USA).
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